Written and first recorded by The Valentinos (US #94/R&B #21 1964).
Other hit version by The Rolling Stones (US #26/UK #1/IRE #2/NZ #2 1964).
From the wiki: “‘It’s All Over Now’ was written by Bobby Womack and Shirley Womack. It was first released by The Valentinos featuring Bobby Womack. The Valentinos version entered the Billboard Hot 100 on June 27, 1964, where it stayed on the chart for two weeks, peaking at #94.
“New York disc jockey Murray the K gave The Stones a copy of The Valentinos’ version and suggested they record it. The Stones recorded this during their first US tour at Chess Studios in Chicago, at a session that also produced ‘Time Is On My Side‘. ‘It’s All Over Now’ became the group’s first UK #1 hit, in July 1964. It was the band’s third single released in America, and stayed in the Billboard Hot 100 for ten weeks, peaking at #26.
“Years later, Bobby Womack said in an interview that he had told his manager he did not want the Rolling Stones to record their version of the song, and that he had told Mick Jagger to get his own song. His manager convinced him to let the Rolling Stones record the song. Six months later on receiving the royalty check for the song he told his manager that Mick Jagger could have any song he wanted.
“Trivia: A popular Australia-based rock combo attempted to appropriate the name of the original Valentinos but had to change their name when faced with the threat of possible litigation by Bobby and his brothers. This group later changed their name to the Lost Valentinos.
“More trivia: This was the first song Bruce Springsteen learned to play on guitar.”
The Rolling Stones, “It’s All Over Now” original mono single (1964):