First performed (in Casino Royale) by Dusty Springfield (1967).
First single release by Nina Simone (1967).
Hit versions by Dusty Springfield (US #22/CAN #26 1967), Sergio Mendes & Brazil ’66 (US #4 1968).
Also recorded by Isaac Hayes (1970).
From the wiki: “‘The Look of Love’ was written by Burt Bacharach, and was originally intended to be an instrumental for the James Bond spook, Casino Royale but, later, Hal David added the lyrics. The song was first recorded by Springfield originally for the Casino Royale soundtrack by Phil Ramone, the soundtrack’s engineer, who recorded the song separately from the rest of the film tracks with Springfield accompanied by only piano, saxophone and percussion.
“Springfield re-recorded the song in London the same year with a more full arrangement, releasing the track as the B-side of ‘Give Me Time’. That version charted in the US and Canada. But, prior to the release of Springfield’s single, Nina Simone recorded and released her own version of ‘The Look of Love’ in 1967 for her album Silk & Soul. Simone’s single had no chart impact.